The continued struggle over biofuel feedstocks March 2022
By Rebecca Guenard
In This Section
- Mimicking mother’s milk
- Three paths forward for sustainable palm oil May 2022
- Is it time to reconsider the role of saturated fats in the human diet? April 2022
- The continued struggle over biofuel feedstocks March 2022
- A new kind of plant breeding February 2022
- The new bio-based surfactant feedstock January 2022
- Lipid role in the immune system November/December 2021
- New essential dietary lipids? October 2021
- Gut Instincts September 2021
- Can computers make better plant-based foods? July/August 2021
- Poisson from a petri dish June 2021
- The latest additions to eco-friendly cleaning May 2021
- Preserving emulsions with plant-based antioxidants April 2021
- Developments in green surfactants for enhanced oil recovery March 2021
- Alternative base oils: a perspective March 2021
- The COVID-19 pandemic, one year later March 2021
- The green machine: commercializing microalgae products February 2021
- Bio-based (edible) oils: feedstock for lubricants of the future January 2021
- The latest on liposomes January 2021
- Fatty acids and athletic performance November/December 2020
- Where are lubricants headed November/December 2020
- New developments in vegetable oil materials science October 2020
- Agriculture at risk: preparing the oilseed industry for a warmer world September 2020
- Science highlights from a cancelled 2020 AM&E July/August 2020
- Managing your career in times of change June 2020
- Lipidomics comes of age May 2020
- Minimally processed oils April 2020
- The high-throughput frontier March 2020
- Nurturing innovation: how AOCS industries are fostering progress February 2020
- The trouble with studying omega-3s and the brain January 2020
- Understanding pulse anti-nutrients January 2020
- Digitizing manufacturing: how companies are using data to improve production November/December 2019
- Weaving together genetics, epigenetics, and the microbiome to optimize human nutrition October 2019
- Taking the cream out of ice cream September 2019
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- Cool characterization methods and where to find them May 2019
- Fermentation, the new protein supply chain April 2019
- Oleogels for drug delivery March 2019
- The complexity of clean-label cosmetics February 2019
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- Trends in synthetic and natural antioxidants for shelf life extension of meat and meat products November/December 2018
- The icing on the cake October 2018
- Enhancing oxidative stability and shelf life of frying oils with antioxidants September 2018
- Under arrest: investigating factors that govern partial coalescence July/August 2018
- Unconventional Oils June 2018
- Beauty from within May 2018
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- Lessons learned from Hurricane Harvey March 2018
- Clean meat February 2018
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- Strategic role of peanuts in sustainable global food security November/December 2017
- Science beyond borders: international student exchange October 2017
- Clean label: the next generation September 2017
- Science snapshots from Orlando July/August 2017
- Five new AOCS methods June 2017
- The whys and wherefores of life-cycle assessment May 2017
- China’s evolving edible oils industry April 2017
- The mysterious case of the arsenolipids March 2017
- Red palm oil February 2017
- The Highs and Lows of Cannabis Testing October 2016
- Chia: Superfood or superfad? January 2017
- Generational training divide November/December 2016
- Storage stability of roasted nuts and stabilization strategy using natural antioxidants September 2016
- Good vibrations: online and at-line monitoring of edible oils with vibrational spectroscopy July/August 2016
- Benchtop NMR spectroscopy for meat authentication June 2016
- Coconut oil boom May 2016
- Sink or swim: fish oil supplements and human health April 2016
- Pulsed electric field: groundbreaking technology for improving olive oil extraction March 2016
- Prescribing dietary fat: therapeutic uses of ketogenic diets February 2016
- Organogels of vegetable oil with plant wax January 2016
- The power of peptides November/December 2015
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- Use of spent bleaching earth for economic and environmental benefit May 2015
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- Development of the first efficient membrane separations of cis fatty acids October 2014
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- Two advances in biodiesel technology July/August 2014
- 2014 AOCS Annual Meeting & Expo July 2014
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- A customized approach to frying oil June 2014
- Omics reveals subtle changes in carbon flux that lead to increased oil biosynthesis in oil palm May 2014
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- Emulsions: making oil and water mix April 2014
- Lipid co-oxidation of proteins: One size does not fit all March 2014
- FSMA marches on March 2014
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- Pathways to novel chemicals February 2014
- Specialty lipids in pet nutrition January 2014
- EFSA releases preliminary report on occurrence of 3-MCPD in food January 2014
- Seven new biobased surfactant technologies November/December 2013
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- Shortage leads to green route to olefins October 2013
- Sesamol: a natural antioxidant for frying oil September 2013
- FSMA update September 2013
- Patent rights and biotech seeds July August 2013
- The other vitamin E July 2013
- Frac fever heats up June 2013
- Fat fight: Catch-22 for Western oleochemicals? June 2013
- Health and Nutrition News April 2013
- FDA asks for fees from industry to fund FSMA June 2013
- What does it take to start a biodiesel industry? April 2013
- What’s in a Claim? Would a Food Not Labeled “Natural” Taste as Sweet? March 2013
- Regulatory overview March 2013
- The preservative wars February 2013
- Plants producing DHA February 2013
- Swift response to paper on feeding GMO corn, glyphosate January 2013
- AOCS: supporting international standards January 2013
- TSCA and the regulation of renewable chemicals July August 2013
- trans Fatty acid content of foods in China January 2013
- A novel green catalytic process for biodiesel production from Jatropha November/December 2012
- The America Invents Act: Groundbreaking US patent law changes are here November/December 2012
- “Super Phos” esters: the key to higher-performance products November/December 2012
- Advances in field-portable mass spectrometers for on-site analytics October 2012
- EFSA sets upper intake level for LC-PUFA October 2012
- Malaysia: economic transformation advances oil palm industry September 2012
- High-oleic canola oils and their food applications September 2012
- Using enzymes to prepare biobased surfactants July/August 2012
- Oilseeds: at the center of food, water, and energy security July/August 2012
- Health & Nutrition News June 2012
- Hydrocolloids get personal June 2012
- The secrets of Belgian chocolate May 2012
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- The Future of LAB March 2012
- World supplies of rapeseed and canola likely to remain tight in the 2012/13 season March 2012
- Methods for differentiating recycled cooking oil needed in China February 2012
- Supercritical fluid-based extraction/processing: then and now February 2012
- Singapore: the place to be in 2012 February 2012
- The Food Safety Modernization Act and its relevance to the oilseed industry February 2012
- Oilseeds in Australia January 2012
- Hydrogen peroxide in home-care formulations November 2011
- A new generation of renewable fuels is on the horizon November 2011
- Omega-3 fatty acids: $13 billion global market October 2011
- Soy and breast cancer October 2011
- EU approves food labeling rules September 2011
- IOM panel recommends tripling vitamin D intake: Panel’s conservative approach receives criticism September 2011
- Self-assembly of lyotropic liquid crystals: from fundamentals to applications August 2011
- Sustainability watch July 2011
- Sustainability Watch July 2011
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- Insect oils: Nutritional and industrial applications May 2011
- Reconstructing formulas April 2011
- US eggs now lower in cholesterol April 2011
- How to control eating behavior--in mice March 2011
- Maybe we don’t know beans March 2011
- Short- and long-term price forecasting for palm and lauric oils February 2011
- New 3-MCPD (glycidol ester) method February 2011
- Regulatory issues associated with the international oils & fats trade January 2011
- Point-counterpoint on UC Davis olive oil report January 2011
- Biomass--The next revolution in surfactants? December 2010
- One person’s response to a high omega-6 diet November 2010
- Crop residues as feedstock for renewable fuels November 2010
- Universal detectors for determination of lipids in biodiesel production October 2010
- New very long chain fatty acid seed oils produced through introduction of strategic genes into Brassica carinata October 2010
- Surfactants based on monounsaturated fatty acids for enhanced oil recovery September 2010
- Questioning the virginity of olive oils September 2010
- Dietary guidelines report released August 2010
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- News from the Expo floor July 2010
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- First high-GLA safflower oil on market June 2010
- AOCS 2.0 debuts June 2010
- Palm fatty acid distillate biodiesel: Next-generation palm biodiesel May 2010
- Palm oil pundit speaks May 2010
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- The ultra-low-linolenic soybean market April 2010
- Dealing with the media: A cautionary tale March 2010
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- Giants of the Past: Hermann Pardun (1908-2009) February 2010
- Q&A with Bill Christie February 2010
- Update on Jatropha January 2010
- Unique properties of carbon dioxide-expanded lipids January 2010
- The market situation and political framework in Germany for biodiesel and vegetable oil December 2009
- Industrial oil crops-when will they finally deliver on their promise ? December 2009
- Chemically enhanced oil recovery stages a comeback November 2009
- Field-portable mass spectrometers for onsite analytics: What's next? October 2009
- To make biofuels, or not to make biofuels:That is the question. September 2009
- Melamine analysis at the forefront September 2009
- Global oil yields: Have we got it seriously wrong? August 2009
- Omega-3 fatty acid profiling and dietary forensics August 2009
- Oilseeds of the future part 3 July 2009
- The rise and fall of surfactants lore July 2009
- Oilseeds of the future: Part 2 June 2009
- Codex Alimentarius Commission update June 2009
- Raw material sources for the long-chain omega-3 market:Trends and sustainability. Part 3. May 2009
- Oilseeds of the future: Part 1 May 2009
- Chloroesters in foods: An emerging issue April 2009
- Raw material sources for the long-chain omega-3 market: Trends and sustainability. Part 2. April 2009
- Synthetic HDL created March 2009
- Raw material sources for the long-chain omega-3 market:Trends and sustainability. Part 1. March 2009
- A convenient way to increase legume intake February 2009
- Vitamin E’s safety controversy January 2009
- Universal mechanism of aging uncovered? January 2009
- Biofuels are becoming a mainstay around the world.
- Analysts believe competition for vegetable oils between food and fuel manufacturers will only increase since feedstock supplies like used cooking oil and tallow are fixed.
- Are non-edible oilseed cover crops likely to provide the next major feedstock?
In 1912, the inventor of the diesel engine, Rudolf Diesel predicted that someday our dependence on petroleum fuels would abate as their supply diminished, creating a market for new fuels sourced from animals and vegetables. That time has arrived.
Emissions from the internal combustion engine contribute to the concentration of carbon dioxide in the atmosphere. Scientists have proven that as the amount of these gases go up they cause a greenhouse effect over the planet, raising its temperature and leading to climate change. To reverse this effect, governments around the world have agreed to reduce their carbon emissions with an eventual net-zero goal (https://unfccc.int/).
The transportation sector, in particular, has been the focus of efforts to lower emissions. More auto manufacturers are adjusting their product line to include electric vehicles, but that will not eliminate the need for cleaner burning fuels. Farm equipment and other heavy machinery are difficult to power with batteries. The same is true for airplanes, which produce a significant amount of carbon. Of the total greenhouse gas emissions produced by the United States, for example, about 3 to 4% comes from aviation (https://tinyurl.com/2p875et6).
Reducing emissions may be a global concern, but the United States confronts unique challenges compared to the rest of the world. “In Europe, they just do not drive as much,” says Bryan Yeh, president and CEO of American Biodiesel Community Fuels based in Walnut Creek, California, USA. Thus, US regulators are pushing harder on fuel refiners to incorporate lower emissions biofuels.
In December 2021, the US Environmental Protection Agency (EPA) proposed a 20% volume increase over 2020 values for its Renewable Fuel Standard program. In the months since, during the allotted comment period before the proposal takes effect, some food manufacturers testified in congressional hearings that the increase would induce market turmoil.
The outcry from food producers once again puts a spotlight on the Achilles’ heel of biofuels: the need for an exclusive, reliable feedstock. How far have producers come in their efforts to find alternatives and are they truly more environmentally friendly?
The term “biofuel” covers a wide range of products, including fuel ethanol, biodiesel, renewable diesel, renewable heating oil, and sustainable aviation fuel (SFA).Compared to their petroleum-based counterparts, all these fuels emit less carbon dioxide when used to produce energy, but they are chemically distinct.
Biodiesel is made through a transesterification reaction which produces glycerin and fatty acid methyl esters. Triglycerides from soybean oil, palm oil, or beef tallow form the methyl ester biodiesel when reacted with methanol in the presence of a catalyst, such as sodium methoxide.
The resulting fuel is an oxygen-containing compound with properties that do not exactly match those of petroleum diesel (https://www.biodiesel.org/). In addition, some feedstocks can form waxy coatings that plug fuel filters in cold weather. Using the right feedstocks help eliminate these problems. In some cases, triglycerides are typically preprocessed to remove any free fatty acids.
Biodiesel is currently produced to specifications set by ASTM International, a standards organization. As a result, says Yeh, “past concerns about its use with new diesel engines are no longer valid.” However, due to its oxygen content, biodiesel has higher NOₓ emissions (Table 1) than other biofuels (https:// doi.org/10.1007/978-1-4419-7145-6_15).
Renewable diesel and SFA, on the other hand, does not contain oxygen. They are hydrocarbon products formed when triglyceride molecules (from feedstocks similar to those mentioned above) react with hydrogen over a metal catalyst. In 2007, the Finish company Neste was the first to produce renewable diesel (also known as Hydrotreated Vegetable Oil or HVO), and it is now the world’s largest producer. The company currently has production sites in Finland, Singapore, and The Netherlands (https://www.neste.us/). They distribute renewable diesel to various locations on the West Coast of North America, and the company says it plans to expand its headquarters in Houston, Texas, USA, to better accommodate these markets.
Too Much, Too Soon?
Neste did not remain the sole provider of renewable diesel for long. In the United States, companies that built refineries to process crude petroleum decades ago during the oil boom have recently repurposed their plants to produce the fuel. According to the production capacity reported by the companies that operate these plants, US renewable diesel production will increase by an order of magnitude in just a few years, from 0.5 billion to 5 billion gallons (https://www.npr.org/transcripts/1043413986).
Although former petroleum refineries are being converted for biofuel production world-wide, economics is driving US companies to make the switch, especially on the West Coast. “California is currently the only state that has The Low Carbon Fuel Standard program that incentives the selling of these products,” says Yeh.
For nearly 20 years, California governors have legislated for the use of cleaner fuels. Most recently, the regulatory goal is to eliminate petroleum diesel emissions by 2030. According to Yeh, that will require 4 billion gallons of diesel equivalent biofuels yearly, for the state of California alone.
With increases in production mandated by the state of California and the US government, food manufacturers say they cannot buy soy and vegetable oils because supplies have gone to transportation. They testified to the US Congress that soybean oil prices more than quadrupled in the last quarter of 2021 due to increased demand by biofuel refineries (https://tinyurl.com/yckzfs8w).
Using 2020 data available from the US Energy Information Administration, Yeh calculated that soybean oil represents over 60% of biodiesel feedstock. And NPR reported that before the recent shift to biodiesel feedstock, a third of US-produced soybean oil was already dedicated to the product. Jeremy Martin, a member of the Union of Concerned Scientists, told NPR he is concerned land where higher carbon capture crops are currently grown will be turned over to soybeans to meet the escalating oil demands.
Yeh says, that is not likely for refineries selling biofuels to California, since they would be leaving money on the table. The state offers credits based on a biofuel’s feedstock since greenhouse gas emissions can worsen or improve depending on the source.
Finding Low Carbon Intensity Feedstocks
Theoretical calculations for indirect land-use changes, or ILUC, first appeared in a paper published in 2008, by Princeton University researchers (https://doi.org/10.1126/science. 1151861). Since then, ILUC has been extensively debated. Its intention is to measure the net change in greenhouse gas emissions when natural land, like rainforests and grasslands, which sequester carbon, are cleared and converted into croplands for biofuels. Despite its initial controversy, ILUC impact is now incorporated into renewable fuel standards in the United States (particularly in California), the United Kingdom, and the European Union.
“In the state of California, biofuel producers earn credits proportional to the carbon intensity of the feedstock used,” says Yeh. “The carbon intensity of soybean oil is almost half of petroleum diesel, but used cooking oil is a quarter.” When the credits for carbon intensity are applied, California producers receive $0.90 more per gallon for used cooking oil feedstock (Table 2). Therefore, there should be less incentive to use soybean oil. Incidentally, the United States Department of Agriculture (USDA) agrees with Yeh, projecting that the demand for soybean oil will remain steady in 2022 (https:// tinyurl.com/bdekz5hz).
Market analysts differ with this opinion based on the fact that there is a limited amount of low-carbon feedstocks. Yeh acknowledges that West Coast ports have the benefit of easier access to shipments of used cooking oil from Asian markets. In general, lower carbon feedstocks are less accessible in landlocked areas where soybean is already being grown.
Analysts also point to the recent partnership between refineries and crushers as an indicator that soybean oil will continue to be a major feedstock. In December of 2021, ADM announced a joint venture with Marathon Petroleum Corp. that will own and operate a soybean processing plant to be built in North Dakota. The plant will exclusively supply oil to the refinery for renewable diesel fuel production (https:// tinyurl.com/mr4253ay). Cargill announced a similar partnership with Paseo Biofuels earlier in the year (https://tinyurl. com/yck9c8s5).
If analysts and bakers are correct about a potential unfulfilled demand for soybean oil, biofuel refineries may have to secure other feedstocks. The market is providing a prime opportunity for a new source of triglycerides.
A New Crop of Feedstocks
For over a decade the USDA has supported research projects across the country aimed at identifying high-yield oilseed crops that could be used to make biofuels. According to news reports, the investment is nearly ready to pay off.
“We know so much more about cover crops than we did five or six years ago,” says Sheeja George, research project manager for the Southeast Partnership for Advanced Renewables from Carinata (SPARC) at the University of Florida in Quincy, Florida, USA. Thanks to a $15 million dollar grant from the USDA’s National Institute of Food and Agriculture, the public-private partnership has researched a traditionally breed mustard seed variety, called Brassica carinata, as a non-edible oilseed crop for the production of biofuels.
“Carinata is about 40% oil, which is on par with soybean,” says George. “And, depending on the variety, the meal is 35–40 % protein that then is available for animal feed markets.”
Since industrial oilseed crops like pennycress, camelina, and carinata are non-edible, their use in the production of biofuels will not affect food manufacturers’ bottom line. In addition, these crops are planted in the off-season when fields are typically idle which means their ILUC is neutral. According to George, carinata is in the process of undergoing US EPA certification to confirm this claim (among others) in preparation for making it eligible for sale in California.
Last May, an EPA representative told the news agency Reuters that camelina has already received approval (https:// tinyurl.com/2s3r4ufz). Canadian seed developers report that popularity of the crop is growing. One producer says camelina oil tripled the company’s sales in 2020.
At the same time, carinata was catching on in South America. In 2020, an Australian agrichemical company sold carinata (brand named Nuseed) to farmers in Argentina for commercial use. In the year since, all the oil produced from Nuseed has been sold to Saipol, a biodiesel producer in Grand- Couronne, France.
And Bayer AG and Bunge have invested millions in funding to develop a gene-edited variety of covercress customized for maximum oil and meal production, along with cold weather hardiness. The start-up the companies are supporting, CoverCress, based in St. Louis, Missouri, USA, has ambitions to plant 3 million acres of the new oilseed by 2030.
When asked what stands in the way of cover crops edging into the biofuel feedstock market, George says: production. Right now, there are not enough farmers planting these oilseed crops. She says there are a few reasons why.
The first is the US government’s policy on agricultural insurance. According to George, a farmer can only claim insurance on a single crop per year. As the policy stands, farmers would have to assume the risk of planting a cover crop should it fail.
The next, possibly greater hurdle is tradition. “In the Southeast, particularly, farmers do not want to risk anything affecting their traditional crops which are cotton and peanuts,” says George. A delayed harvest from a winter cover crop could negatively impact the start of planting preparations for their primary crops. “It will take early adopters to spread, by word of mouth, that they increased their soil health and their yearly revenue by planting cash-cover crops, like carinata,” she says.
Finally, the cover crop means more work for the farmers. In the past, says George, after a fall harvest, farmers would spray down weeds and then take a break for a few months before preparing their summer crop. She says more farmers are shifting to the year-round farming necessary to maintain a cover crop, but the culture change will be slow until there is proof of a decent financial benefit for the extra effort.
Until carinata production increases, crushers may not be convinced to accommodate the crop in their facility to produce the oil needed for biofuels. Between processing an edible and non-edible oil the equipment must be thoroughly cleaned. High enough production could prompt processors to build new crush facilities and eventually establish a local supply chain.
New feedstocks cannot come too soon. In the US, emissions are back on the rise. Pandemic lockdowns in 2020 resulted in a 10% drop, but in 2021 they rebounded 6.2%. They are now just 17.4% below 2005 levels, well short of the 50% decrease the country hopes to achieve before 2030 (https:// tinyurl.com/38ywxxmj).
Yeh says, although some US automakers are rethinking their engine designs, most of the car manufactures in Europe and China are making a greater commitment to electrification. Demand might not grow as fast in these regions. In the next five years current feedstock challenges are likely to peak, particularly in the Americas.
About the Author
Rebecca Guenard is the associate editor of Inform at AOCS. She can be contacted at email@example.com